NDLI: DMC Formation over Ce0.5Zr0.5O2 Prepared by Complex-decomposition Method

Content Provider	Springer Nature Link
Author	Zhang, Zhi Fang Liu, Zhao Tie Liu, Zhong Wen Lu, Jian
Copyright Year	2008
Abstract	The Ce0.5Zr0.5O2 solid solution was prepared by a complex-decomposition method using different organic acids as complexants and cerium and zirconium nitrides as precursors, respectively. The characterization results of XRD, Raman, SEM, H2-TPR, CO2-TPD, N2 adsorption at 77 K indicate that the physical properties of the solid solutions were significantly affected by the complexants used. These solid solutions can be used in dimethyl carbonate (DMC) synthesis from methanol and CO2. Results indicate that crystal structure of Ce0.5Zr0.5O2 was the key factor in determining the catalytic activity for DMC synthesis. Moreover, the catalytic activity of the Ce0.5Zr0.5O2 was significantly decreased when phase separation as a result of the enrichment either of Ce or Zr was occurred. The BET surface area, the redox behavior, and pore properties of the solid solution, depending on the complexants used and the calcination temperature, also played less important roles in determining the catalytic activity for the titled reaction. The optimized Ce0.5Zr0.5O2 showed high activity for the direct synthesis of DMC from CO2 and methanol.
Starting Page	428
Ending Page	436
Page Count	9
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	129
Issue Number	3-4
e-ISSN	1572879X
Language	English
Publisher	Springer US
Publisher Date	2008-12-23
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Ce0.5Zr0.5O2 DMC synthesis Complex-decomposition method CO2 CH3OH Adipic acid Pharmacy Industrial Chemistry/Chemical Engineering Physical Chemistry Catalysis
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Synthesis of DMC from CH3OH and CO2 over Ce0.5Zr0.5O2 Catalysts

Methanol synthesis over Cu/ZnO catalysts prepared by ball milling

Methanol decomposition to synthesis gas over supported Pd catalysts prepared from synthetic anionic clays

CO2 Hydrogenation to Methanol Over Cu/ZnO/Al2O3 Catalysts Prepared by a Novel Gel-Network-Coprecipitation Method

The Partial Oxidation of CH3OH to CO2 and H2 Over a Cu/ZnO/Al2O3 Catalyst

Methanol synthesis from carbon monoxide and hydrogen catalyzed over Pd/CeO2 prepared by the deposition–precipitation method

Methanol Decomposition to Synthesis Gas Over Supported Pd Catalysts Prepared from Hydrotalcite Precursors

Gas-phase decomposition of formic acid over Fe2O3 catalysts

Methanol Synthesis from Carbon Monoxide and Hydrogen over Ceria-Supported Copper Catalyst Prepared by a Coprecipitation Method

DMC Formation over Ce0.5Zr0.5O2 Prepared by Complex-decomposition Method

Similar Documents

Synthesis of DMC from CH3OH and CO2 over Ce0.5Zr0.5O2 Catalysts

Methanol synthesis over Cu/ZnO catalysts prepared by ball milling

Methanol decomposition to synthesis gas over supported Pd catalysts prepared from synthetic anionic clays

CO2 Hydrogenation to Methanol Over Cu/ZnO/Al2O3 Catalysts Prepared by a Novel Gel-Network-Coprecipitation Method

The Partial Oxidation of CH3OH to CO2 and H2 Over a Cu/ZnO/Al2O3 Catalyst

Methanol synthesis from carbon monoxide and hydrogen catalyzed over Pd/CeO2 prepared by the deposition–precipitation method

Methanol Decomposition to Synthesis Gas Over Supported Pd Catalysts Prepared from Hydrotalcite Precursors

Gas-phase decomposition of formic acid over Fe2O3 catalysts

Methanol Synthesis from Carbon Monoxide and Hydrogen over Ceria-Supported Copper Catalyst Prepared by a Coprecipitation Method

DMC Formation over Ce0.5Zr0.5O2 Prepared by Complex-decomposition Method