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| Content Provider | Springer Nature Link |
|---|---|
| Author | Klein, Kati Kivi, Arthur Dulova, Niina Zekker, Ivar Mölder, Erik Ten, Toomas Trapido, Marina Ten, Taavo |
| Copyright Year | 2016 |
| Abstract | This pilot study describes a three-stage continuous process for treating landfill leachate containing significant concentrations of recalcitrant organic substances. The proposed technological scheme consisted of an activated sludge pre-treatment combined with a Fenton-like process enhanced by continuous sludge reuse and followed by an activated sludge post-oxidation. Biological pre-treatment removed >99, 86, >99, 83 and 86 % of BOD7, COD, NH4 +–N, phenols and the sum of lignin and tannins, respectively. Operational conditions in the ferric sludge-catalysed Fenton-like process stage were carefully adjusted in order to maintain the efficacy and practicability of combined treatment scheme. Although the application of ferric sludge as a catalyst in the Fenton-like oxidation reduced COD removal efficiency by 32 % as compared to the conventional Fenton process, lower process efficiency was compensated by reducing the water exchange ratio to 50 % without increasing the consumption of reagents. Moreover, an intermittent addition (added to every second treatment cycle) of fresh ferrous iron catalyst at a H2O2/Fe2+ w/w ratio of 20/1 increased the BOD7/COD ratio from 0.04 to 0.32 and resulted in 60 % COD removal. A cyclic addition (added to every treatment cycle) of the same amount of catalyst increased the BOD7/COD ratio from 0.09 to 0.32, and a 10 % higher COD removal efficiency as compared to intermittent catalyst addition was achieved. Finally, biological post-treatment of the leachate resulted in more than 95 % removal of each measured parameter. Overall, the combined technological scheme with continuous ferric sludge reuse in the Fenton-like stage proved promising alternative for landfill leachate treatment. |
| Starting Page | 541 |
| Ending Page | 551 |
| Page Count | 11 |
| File Format | |
| ISSN | 1618954X |
| Journal | Clean Technologies and Environmental Policy |
| Volume Number | 19 |
| Issue Number | 2 |
| e-ISSN | 16189558 |
| Language | English |
| Publisher | Springer Berlin Heidelberg |
| Publisher Date | 2016-07-05 |
| Publisher Place | Berlin, Heidelberg |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Combined treatment Landfill leachate Fenton-like process Biological treatment Ferric sludge reuse Water exchange ratio Sustainable Development Industrial Chemistry/Chemical Engineering Industrial and Production Engineering Environmental Engineering/Biotechnology Environmental Economics |
| Content Type | Text |
| Resource Type | Article |
| Subject | Environmental Chemistry Environmental Engineering Economics and Econometrics Business, Management and Accounting Management, Monitoring, Policy and Law |
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