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  1. Monatshefte für Chemie - Chemical Monthly
  2. Monatshefte für Chemie - Chemical Monthly : Volume 131
  3. Monatshefte für Chemie - Chemical Monthly : Volume 131, Issue 12, December 2000
  4. Rhodium-Catalyzed Amination of Aromatic Olefins [1]
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Monatshefte für Chemie - Chemical Monthly : Volume 148
Monatshefte für Chemie - Chemical Monthly : Volume 147
Monatshefte für Chemie - Chemical Monthly : Volume 146
Monatshefte für Chemie - Chemical Monthly : Volume 145
Monatshefte für Chemie - Chemical Monthly : Volume 144
Monatshefte für Chemie - Chemical Monthly : Volume 143
Monatshefte für Chemie - Chemical Monthly : Volume 142
Monatshefte für Chemie - Chemical Monthly : Volume 141
Monatshefte für Chemie - Chemical Monthly : Volume 140
Monatshefte für Chemie - Chemical Monthly : Volume 139
Monatshefte für Chemie - Chemical Monthly : Volume 138
Monatshefte für Chemie - Chemical Monthly : Volume 137
Monatshefte für Chemie - Chemical Monthly : Volume 136
Monatshefte für Chemie - Chemical Monthly : Volume 135
Monatshefte für Chemie - Chemical Monthly : Volume 134
Monatshefte für Chemie - Chemical Monthly : Volume 133
Monatshefte für Chemie - Chemical Monthly : Volume 132
Monatshefte für Chemie - Chemical Monthly : Volume 131
Monatshefte für Chemie - Chemical Monthly : Volume 131, Issue 12, December 2000
Editorial
Preface
Facile Hydrogenation of Acenapthylenes and Azulenes on the Face of a Triruthenium Carbonyl Moiety: Discovery of Specific Reactions on the Cluster Framework Providing Unique Insight for Cluster Catalysis
Recent Chemistry Based on the [RuCp(CH3CN)3]+ Cation: Reappraisalof an Old Precursor
Syntheses and Crystal Structures of Polynuclear Cu(I) Complexes Containing the 1,1′-Bis-(diphenylphosphino)-ferrocene Ligand
Synthesis, Characterization, and Fluxional Behaviour of Binuclear Palladium Complexes with a Half-A-Frame Structure
Palladium Chemistry Related to Benzyl Bromide Carbonylation: Mechanistic Studies
Mechanism of the Nickel-Catalyzed Electrosynthesis of Ketones by Heterocoupling of Acyl and Benzyl Halides
A Novel Infinite 1-D Chain of Silver(I) Bridged by trans-Azobenzene
Analysis of the Solid-State Rearrangementof Hydrido-Alkynyl Ruthenium Complexesto their Vinylidene Tautomers
Oxidation of Alcohols by [Cp*Rh(ppy)(OH)]+
Rhodium-Catalyzed Amination of Aromatic Olefins [1]
Enantioselective Homogeneous Hydrogenation of Monosubstituted Pyridines and Furans
Iridium(I)-Catalyzed Asymmetric Intermolecular Hydroarylation of Norbornene with Benzamide
Synthesis, Characterization, and Catalytic Activity of Rh(I) Complexes with (S)-BINAPO, an Axially Chiral Inducer Capable of Hemilabile P,O-Heterobidentate Coordination
Chiral Steroidal Phosphines: Synthesis and Platinum Complexes
Enantioselektive Katalysen, 135. Mitt. [1]. Stereoselektive Hydrierung von Folsaüure und2-Methylchinoxalin mit optisch aktiven Rhodium(I)-Phosphan-Komplexen
Monatshefte für Chemie - Chemical Monthly : Volume 131, Issue 11, November 2000
Monatshefte für Chemie - Chemical Monthly : Volume 131, Issue 10, October 2000
Monatshefte für Chemie - Chemical Monthly : Volume 131, Issue 9, September 2000
Monatshefte für Chemie - Chemical Monthly : Volume 131, Issue 8, August 2000
Monatshefte für Chemie - Chemical Monthly : Volume 131, Issue 7, July 2000
Monatshefte für Chemie - Chemical Monthly : Volume 131, Issue 6, June 2000
Monatshefte für Chemie - Chemical Monthly : Volume 131, Issue 5, May 2000
Monatshefte für Chemie - Chemical Monthly : Volume 131, Issue 3, March 2000
Monatshefte für Chemie - Chemical Monthly : Volume 131, Issue 2, February 2000
Monatshefte für Chemie - Chemical Monthly : Volume 131, Issue 4, January 2000
Monatshefte für Chemie - Chemical Monthly : Volume 131, Issue 1, January 2000
Monatshefte für Chemie - Chemical Monthly : Volume 130
Monatshefte für Chemie - Chemical Monthly : Volume 129
Monatshefte für Chemie - Chemical Monthly : Volume 128

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Rhodium-Catalyzed Amination of Aromatic Olefins [1]

Content Provider Springer Nature Link
Author Tillack, Annegret Trauthwein, Harald Hartung, Christian G. Eichberger, Martin Pitter, Stephan Jansen, Achim Beller, Matthias
Copyright Year 2000
Abstract  The oxidative amination of styrene with secondary amines in the presence of cationic rhodium catalysts yields regiospecifically the corresponding anti-Markovnikov enamines. Styrene as the hydrogen acceptor gave concomitantly ethylbenzene. In the presence of 1,5-cyclooctadiene (cod) preferential reduction to cyclooctene takes place. The addition of cod reduces the rate of the reaction, but also the amount of ethylbenzene produced. Here, for the first time the ratio of enamine: ethylbenzene is > 1, which is favourable in case of more expensive styrene derivatives. A screening of various ligands for oxidative amination reveals that hemilabile 2-(ω-phosphino-n-alkyl)-pyridines are superior ligands for this reaction compared to simple alkyl and aryl phosphines.
Starting Page 1327
Ending Page 1334
Page Count 8
File Format PDF
ISSN 00269247
Journal Monatshefte für Chemie - Chemical Monthly
Volume Number 131
Issue Number 12
e-ISSN 14344475
Language English
Publisher Springer-Verlag
Publisher Date 2000-12-13
Publisher Place Wien
Access Restriction One Nation One Subscription (ONOS)
Content Type Text
Resource Type Article
Subject Chemistry
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