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| Content Provider | Springer Nature Link |
|---|---|
| Author | Habibi, Biuck Jahanbakhshi, Mojtaba Pournaghiazar, Mohammad Hossein |
| Copyright Year | 2010 |
| Abstract | Carbon-ceramic electrodes (CCE) modified with carbon nanotubes were prepared, and the electrochemical behavior towards acetaminophen (ACOP) was investigated using both a bare CCE and electrodes modified with either single walled carbon nanotubes (SWCNT) or multi walled carbon nanotubes (MWCNT) in an effort to understand which of them is the better choice in terms of electrocatalyzing the oxidation of ACOP, and thus for sensing it. The SWCNT are found to be the better material in significantly enhancing the oxidation peak current and improving the reversibility of the oxidation. Under optimal conditions, linearity between the oxidation peak current and the concentration of ACOP is obtained for the concentration range from 40 nM to 85 μM, with a detection limit of 25 nM. Finally, ACOP was successfully determined with the SWCNT modified electrode in pharmaceutical samples. Cyclic voltammograms recorded at the bare CCE (1, 4); MWCNT/CCE (2, 5); SWCNT/CCE (3, 6) in 0.1 M phosphate buffer solution of pH 7.0 in the absence and in the presence of 4.0 mM ACOP, respectively. Scan rate: 50 mV s-1. |
| Starting Page | 147 |
| Ending Page | 154 |
| Page Count | 8 |
| File Format | |
| ISSN | 00263672 |
| Journal | Microchimica Acta |
| Volume Number | 172 |
| Issue Number | 1-2 |
| e-ISSN | 14365073 |
| Language | English |
| Publisher | Springer Vienna |
| Publisher Date | 2010-10-09 |
| Publisher Place | Vienna |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Acetaminophen Electrocatalysis Nanomolar detection Carbon nanotubes Carbon-ceramic electrode Microengineering Analytical Chemistry Characterization and Evaluation of Materials Nanotechnology Nanochemistry |
| Content Type | Text |
| Resource Type | Article |
| Subject | Analytical Chemistry |
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