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| Content Provider | Springer Nature Link |
|---|---|
| Author | Zhang, Fuhua Yuan, Yawen Zheng, Yiqun Wang, Hua Liu, Tonghao Hou, Shifeng |
| Copyright Year | 2017 |
| Abstract | Reduced graphene oxide hollow microspheres (rGO HMS) were encapsulated with gold nanoparticles (AuNPs) by spray drying. Scanning electron microscopy, transmission electron microscopy, X-ray diffraction and Raman spectroscopy were used to characterize the AuNP/rGO HMS. When placed on a glassy carbon electrode (GCE), it exhibits excellent electrochemical catalytic properties towards the oxidation of nitrite. The electrocatalytic properties were studied using various electrochemical techniques. Compared to AuNP-decorated graphene sheet based electrodes documented in the literature, the one presented here provides a larger surface area. This enhances the catalytic activity towards nitrite. The electrode, typically operated at a working potential of 0.82 V (vs. SCE), has a linear response in the 5.0 μM to 2.6 mM nitrate concentration range, and a detection limit as low as 0.5 μM (at an S/N ratio of 3). Graphical abstract Schematic presentation of the synthesis of graphene hollow microspheres encapsulated with of gold nanoparticles (AuNP/rGO HMS) through a spray drying technique. The material was applied to the electrochemical determination of nitrite. |
| Starting Page | 1565 |
| Ending Page | 1572 |
| Page Count | 8 |
| File Format | |
| ISSN | 00263672 |
| Journal | Microchimica Acta |
| Volume Number | 184 |
| Issue Number | 6 |
| e-ISSN | 14365073 |
| Language | English |
| Publisher | Springer Vienna |
| Publisher Date | 2017-04-18 |
| Publisher Place | Vienna |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Composite materials AuNPs Cyclic voltammetry Spray drying Electrocatalysis Nanochemistry Nanotechnology Characterization and Evaluation of Materials Analytical Chemistry Microengineering |
| Content Type | Text |
| Resource Type | Article |
| Subject | Analytical Chemistry |
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