NDLI: Preparation and properties of poly(butyl methacrylate/lauryl methacrylate) and its blend fiber

Content Provider	Springer Nature Link
Author	Zhao, Jian Xiao, Changfa Xu, Naiku Ma, Xiao
Copyright Year	2012
Abstract	The functionalized copolymers, based on butyl methacrylate (BMA), and lauryl methacrylate (LMA) with crosslinking agent HEMA (hydroxyethyl methacrylate) or DVB (divinyl benzene), have been innovatively synthesized by suspension polymerization for oil absorption. Further, the copolymers and polypropylene (PP) blend fiber were attained via melt spinning. Swelling behaviors were evaluated by equilibrium swelling experiment, oil absorbency test, gel fraction measurement, and optical observations in toluene. The thermal properties and morphologies of the blend fibers were analyzed by thermogravimetry (TGA) and a field-emission scanning electron microscope, respectively. The results show that the copolymers and their blend fibers have an impressive absorbency. PBMA/LMA/HEMA can be up to 35.18 g/g, showing the highest absorption in trichloroethylene. Optical images of swollen polymers in toluene depicted a colloidal translucence with gel structure. Thermogravimetric measurement demonstrates that the copolymer and PP are incompatible and PBMA/LMA/DVB component possesses more thermal stability. The micrographs of the blend fibers exhibit coarse surface and porous cross-section, which leads to the fibers being much more readily wetted by oil and provides a huge space for oil storage.
Starting Page	733
Ending Page	746
Page Count	14
File Format	PDF
ISSN	01700839
Journal	Polymer Bulletin
Volume Number	69
Issue Number	6
e-ISSN	14362449
Language	English
Publisher	Springer-Verlag
Publisher Date	2012-05-23
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Crosslink Swell Hydroxyethyl methacrylate Melt spinning Polypropylene Oil absorbency Characterization and Evaluation of Materials Soft and Granular Matter, Complex Fluids and Microfluidics Polymer Sciences Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry Condensed Matter Physics Polymers and Plastics

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