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Total synthesis of amorfrutin B via a Pd-catalyzed regioselective geranyl migration-decarboxylation-cycloaromatization cascade
| Content Provider | Semantic Scholar |
|---|---|
| Author | Wang, Chao Kong, Yajun Qiao, Hongyun |
| Copyright Year | 2015 |
| Abstract | A biomimetic total synthesis of amorfrutin B, a resorcylate with geranyl bibenzyl scaffold, has been completed in eight steps from 2,2,6-trimethyl-4H-1,3-dioxin-4-one. The key step utilized a highly regioselective Pd-catalyzed geranyl migration-decarboxylation-cycloaromatization cascade. The methodology should be of practical utility in the construction of geranyl bibenzyl scaffolds manifested in many natural products. |
| File Format | PDF HTM / HTML |
| DOI | 10.3998/ark.5550190.p009.162 |
| Volume Number | 2015 |
| Alternate Webpage(s) | http://www.arkat-usa.org/get-file/54645/ |
| Alternate Webpage(s) | https://quod.lib.umich.edu/cgi/p/pod/dod-idx/5550190.p009.162.pdf?c=ark&format=pdf&idno=5550190.p009.162 |
| Alternate Webpage(s) | https://doi.org/10.3998/ark.5550190.p009.162 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
