NDLI: Asymmetric Total Synthesis of (+)-(3E)-Pinnatifidenyne via Abnormally Regioselective Pd(0)-Catalyzed Endocyclization.

Content Provider	Semantic Scholar
Author	Kim, Hyun Je Kim, Taewoo Ahn, Jungmin Yun, Hwayoung Lim, Changjin Jang, Jaebong Sim, Jaehoon An, Hongchan Surh, Young-Joon Lee, Jeeyeon Suh, Young-Ger
Copyright Year	2018
Abstract	The asymmetric total synthesis of the marine natural product (+)-(3E)-pinnatifidenyne was accomplished. The key features of the synthesis involve the construction of an eight-membered cyclic ether by the abnormally regioselective Pd(0)-catalyzed cyclization, the installation of a double bond in the oxocene skeleton by sequential in situ deconjugative isomerization, and the efficient introduction of the crucial chloride mediated by the substrate-controlled diastereoselective reduction.
Starting Page	1997
Ending Page	2005
Page Count	9
File Format	PDF HTM / HTML
DOI	10.1021/acs.joc.7b02937
PubMed reference number	29327583
Journal	Medline
Volume Number	83
Issue Number	4
Alternate Webpage(s)	http://hosting03.snu.ac.kr/~suhlab/2008/pub/161.pdf
Alternate Webpage(s)	https://doi.org/10.1021/acs.joc.7b02937
Journal	The Journal of organic chemistry
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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Asymmetric Total Synthesis of (+)-(3E)-Pinnatifidenyne via Abnormally Regioselective Pd(0)-Catalyzed Endocyclization.