NDLI: Chiral tether-mediated stabilization and helix-sense control of complementary metallo-double helices† †Electronic supplementary information (ESI) available: Experimental details and additional spectroscopic data. See DOI: 10.1039/c4sc02275k Click here for additional data file.

Please wait, while we are loading the content...

Chiral tether-mediated stabilization and helix-sense control of complementary metallo-double helices† †Electronic supplementary information (ESI) available: Experimental details and additional spectroscopic data. See DOI: 10.1039/c4sc02275k Click here for additional data file.

Content Provider	Semantic Scholar
Author	Horie, Miki Ousaka, Naoki Taura, Daisuke Yashima, Eiji
Copyright Year	2015
Abstract	A series of novel PtII-linked double helices were prepared by inter- or intrastrand ligand-exchange reactions of the complementary duplexes composed of chiral or achiral amidine dimer and achiral carboxylic acid dimer strands joined by trans-PtII-acetylide complexes with PPh3 ligands using chiral and achiral chelating diphosphines. The structure and stability of the PtII-linked double helices were highly dependent on the diphosphine structures. An interstrand ligand exchange took place with chiral and achiral 1,3-diphosphine-based ligands, resulting in trans-PtII-bridged double helices, whose helical structures were quite stable even in dimethyl sulfoxide (DMSO) due to the interstrand cross-link, whereas a 1,2-diphosphine-based ligand produced non-cross-linked cis-PtII-linked duplexes, resulting from an intrastrand ligand-exchange that readily dissociated into single strands in DMSO. When enantiopure 1,3-diphosphine-based ligands were used, the resulting trans-PtII-bridged double helices adopted a preferred-handed helical sense biased by the chirality of the bridged diphosphines. Interestingly, the interstrand ligand exchange with racemic 1,3-diphosphine toward an optically-active PtII-linked duplex, composed of chiral amidine and achiral carboxylic acid strands, was found to proceed in a diastereoselective manner, thus forming complete homochiral trans-PtII-bridged double helices via a unique chiral self-sorting.
Starting Page	714
Ending Page	723
Page Count	10
File Format	PDF HTM / HTML
DOI	10.1039/c4sc02275k
PubMed reference number	28706634
Journal	Medline
Volume Number	6
Alternate Webpage(s)	http://pubs.rsc.org/en/content/articlepdf/2015/sc/c4sc02275k?page=search
Alternate Webpage(s)	http://pubs.rsc.org/en/content/articlepdf/2015/sc/c4sc02275k
Alternate Webpage(s)	http://www.rsc.org/suppdata/sc/c4/c4sc02275k/c4sc02275k1.pdf
Alternate Webpage(s)	https://doi.org/10.1039/c4sc02275k
Journal	Chemical science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Bromopyridazinedione-mediated protein and peptide bioconjugation† †Electronic supplementary information (ESI) available: Full experimental details and characterisation. See DOI: 10.1039/c1cc12807h Click here for additional data file.

Regulating the modulus of a chiral liquid crystal polymer network by light† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sm00114a Click here for additional data file. Click here for additional data file.

Dynamic multicolor protein labeling in living cells† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc01364g Click here for additional data file. Click here for additional data file. Click here for additional data file.

A complementary pair of enantioselective switchable organocatalysts† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc02462b Click here for additional data file.

Visible light mediated metal-free thiol–yne click reaction† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc02132h Click here for additional data file.

Synthesis and activity of a novel inhibitor of nonsense-mediated mRNA decay† †Electronic supplementary information (ESI) available: Experimental procedures and spectroscopic data. See DOI: 10.1039/c5ob02482j Click here for additional data file.

Chiral phosphine-mediated intramolecular [3 + 2] annulation: enhanced enantioselectivity by achiral Brønsted acid† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc00952f Click here for additional data file.

Kinase-templated abiotic reaction† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc01416c Click here for additional data file.

Chiral tether-mediated stabilization and helix-sense control of complementary metallo-double helices† †Electronic supplementary information (ESI) available: Experimental details and additional spectroscopic data. See DOI: 10.1039/c4sc02275k Click here for additional data file.

Similar Documents

Bromopyridazinedione-mediated protein and peptide bioconjugation† †Electronic supplementary information (ESI) available: Full experimental details and characterisation. See DOI: 10.1039/c1cc12807h Click here for additional data file.

Regulating the modulus of a chiral liquid crystal polymer network by light† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sm00114a Click here for additional data file. Click here for additional data file.

Dynamic multicolor protein labeling in living cells† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc01364g Click here for additional data file. Click here for additional data file. Click here for additional data file.

A complementary pair of enantioselective switchable organocatalysts† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc02462b Click here for additional data file.

Visible light mediated metal-free thiol–yne click reaction† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc02132h Click here for additional data file.

Synthesis and activity of a novel inhibitor of nonsense-mediated mRNA decay† †Electronic supplementary information (ESI) available: Experimental procedures and spectroscopic data. See DOI: 10.1039/c5ob02482j Click here for additional data file.

Chiral phosphine-mediated intramolecular [3 + 2] annulation: enhanced enantioselectivity by achiral Brønsted acid† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc00952f Click here for additional data file.

Kinase-templated abiotic reaction† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc01416c Click here for additional data file.

Chiral tether-mediated stabilization and helix-sense control of complementary metallo-double helices† †Electronic supplementary information (ESI) available: Experimental details and additional spectroscopic data. See DOI: 10.1039/c4sc02275k Click here for additional data file.