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Phosphine-catalyzed one-pot isomerization of 3-alkynoates and [2 + 3]-cycloaddition with imines: formal synthesis of Securinegaalkaloid (±)-allosecurinine
| Content Provider | Semantic Scholar |
|---|---|
| Author | Sampath, Magesh Lee, Pei-Ying Beatrix Loh, Teck-Peng |
| Copyright Year | 2011 |
| Abstract | Trimethylphosphine-induced isomerization and cycloaddition of 3-alkynoates with imines for the synthesis of 2,5-syn di-substituted pyrrolines were described. In addition, the utility of this protocol was demonstrated in the efficient formal synthesis of the Securinegaalkaloid ‘allosecurinine’. |
| Starting Page | 1988 |
| Ending Page | 1991 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C1SC00311A |
| Volume Number | 2 |
| Alternate Webpage(s) | http://www.ugcfrp.ac.in/images/userfiles/53357-3.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C1SC00311A |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |