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Phosphine-Catalyzed Intramolecular Formal [3+2] Cycloaddition
| Content Provider | Scilit |
|---|---|
| Author | Tang, Y. |
| Editor | Ye, L. -W. Sun, X. -L. Wang, Q. -G. |
| Copyright Year | 2007 |
| Description | The authors report a phosphine-catalyzed intramolecular diastereoselective formal [3+2] cycloaddition for the construction of bicyclo [4.3.0] and [3.3.0] ring systems. A mixture of triphenyl phosphine and $Na_{2}CO_{3}$ was suitable for the generation of bicyclo[4.3.0] compounds, and the combination of triphenyl phosphine and $Cs_{2}CO_{3}$ was found to be the best condition for the construction of [3.3.0] ring systems. With 20 mol% of the triphenyl phosphine catalyst, good to excellent yields were obtained for different substrates. |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2007-968999.pdf |
| Ending Page | 1101 |
| Page Count | 1 |
| Starting Page | 1101 |
| ISSN | 18611958 |
| e-ISSN | 1861194X |
| DOI | 10.1055/s-2007-968999 |
| Journal | Synfacts |
| Issue Number | 10 |
| Volume Number | 2007 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2007-09-19 |
| Access Restriction | Open |
| Subject Keyword | Journal: Synfacts Organic Chemistry Catalyzed Intramolecular Diastereoselective |
| Content Type | Text |
| Resource Type | Article |