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Aromatic “Redox Tag”-assisted Diels–Alder reactions by electrocatalysis† †Electronic supplementary information (ESI) available: Additional figures, tables and general, experimental, theoretical and spectral information. See DOI: 10.1039/c6sc02117d Click here for additional data file.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Okada, Yohei Yamaguchi, Yusuke Ozaki, Atsushi Chiba, Kazuhiro |
| Copyright Year | 2016 |
| Abstract | Electrocatalysis was employed to promote Diels–Alder reactions between electronically mismatched substrates. A catalytic amount of electricity was enough to complete the overall reactions and GC-MS monitoring and CV measurements clearly illustrated the electrocatalytic nature of the reactions, which involve an EC-backward-E mechanism. The electrocatalytic Diels–Alder reactions were rationally designed based on the concept of redox tags. The results were supported by DFT calculations. |
| Starting Page | 6387 |
| Ending Page | 6393 |
| Page Count | 7 |
| File Format | PDF HTM / HTML |
| PubMed reference number | 28451094 |
| Volume Number | 7 |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2016/sc/c6sc02117d |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c6/sc/c6sc02117d/c6sc02117d1.pdf |
| Journal | Chemical Science |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
