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Dehydrogenative Cross-Coupling of Primary Alcohols To Form Cross-Esters Catalyzed by a Manganese Pincer Complex
| Content Provider | Semantic Scholar |
|---|---|
| Author | Das, Uttam Kumar Ben-David, Yehoshoa Leitus, Gregory Diskin-Posner, Yael Milstein, David |
| Copyright Year | 2019 |
| Abstract | Base-metal-catalyzed dehydrogenative cross-coupling of primary alcohols to form cross-esters as major products, liberating hydrogen gas, is reported. The reaction is catalyzed by a pincer complex of earth-abundant manganese in the presence of catalytic base, without any hydrogen acceptor or oxidant. Mechanistic insight indicates that a dearomatized complex is the actual catalyst, and indeed this independently prepared dearomatized complex catalyzes the reaction under neutral conditions. |
| Starting Page | 479 |
| Ending Page | 484 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/acscatal.8b04585 |
| Volume Number | 9 |
| Alternate Webpage(s) | http://www.weizmann.ac.il/Organic_Chemistry/milstein/sites/Organic_Chemistry.milstein/files/uploads/acscatal_dehydrogenative_cross-coupling_of_primary_alcohols_.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/acscatal.8b04585 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
