NDLI: Aldehyde effect and ligand discovery in Ru-catalyzed dehydrogenative cross-coupling of alcohols to esters.

Content Provider	Semantic Scholar
Author	Jiang, Xiaolin Zhang, Jiahui Zhao, Dongmei Li, Yuehui
Copyright Year	2019
Abstract	The presence of different aldehydes is found to have a significant influence on the catalytic performance when using PN(H)P type ligands for dehydrogenation of alcohols. Accordingly, hybrid multi-dentate ligands were discovered based on an oxygen-transfer alkylation of PNP ligands by aldehydes. The relevant Ru-PNN(PO) system provided the desired unsymmetrical esters in good yields via acceptorless dehydrogenation of alcohols. Hydrogen bonding interactions between the phosphine oxide moieties and alcohol substrates likely assisted the observed high chemoselectivity.
Starting Page	2797
Ending Page	2800
Page Count	4
File Format	PDF HTM / HTML
DOI	10.1039/c8cc10315a
Alternate Webpage(s)	http://www.rsc.org/suppdata/c8/cc/c8cc10315a/c8cc10315a1.pdf
PubMed reference number	30758354
Alternate Webpage(s)	https://doi.org/10.1039/c8cc10315a
Journal	Medline
Volume Number	55
Issue Number	19
Journal	Chemical communications
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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