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Tris(1,10-phenanthroline-κ2 N,N′)zinc(II) bis(4-bromobenzoate) 6.5-hydrate
| Content Provider | Semantic Scholar |
|---|---|
| Author | Ye, Su-Fang Zhang, Biyue |
| Copyright Year | 2010 |
| Abstract | In the title compound, [Zn(C(12)H(8)N(2))(3)](C(7)H(4)BrO(2))(2)·6.5H(2)O, the Zn(II) atom is coordinated by six N atoms from three 1,10-phenanthroline (phen) mol-ecules in a distorted octa-hedral geometry. The chelating phen ligands exhibit nearly perfect coplanarity (r.m.s. deviations of 0.048, 0.039 and 0.061 Å). The mean inter-planar distances of 3.51 (2) and 3.54 (4) Å between adjacent phen ligands indicate π-π stacking inter-actions, which connect the complex cations into chains along [101]. The 4-bromo-benzoate anions and the uncoordinated water mol-ecules, parts of which are not fully occupied, are linked by O-H⋯O hydrogen bonds. Two carboxyl-ate O atoms and one Br atom in the 4-bromo-benzoate anions are each disordered over two sites with occupancy factors of 0.60 and 0.40. |
| Starting Page | m474 |
| Ending Page | m474 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| PubMed reference number | 21580556v1 |
| DOI | 10.1107/s1600536810010561 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Volume Number | 66 |
| Alternate Webpage(s) | http://journals.iucr.org/e/issues/2010/04/00/hy2291/hy2291.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536810010561 |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | 1,10-phenanthroline 101 Mouse Alkyl (C12-15) Benzoate Anions Benzoates Bromides Carboxyl Group Cations Chelating Activity Distance Iron Chelating Agents Ligands Mole, unit of measurement octa-valinomycin |
| Content Type | Text |
| Resource Type | Article |
