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Diaquabis(4-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN 1)manganese(II)
| Content Provider | Semantic Scholar |
|---|---|
| Author | Necefoğlu, Hacali Özbek, Füreya Elif Öztürk, Vijdan Adıgüzel, Vedat Hökelek, Tuncer |
| Copyright Year | 2011 |
| Abstract | In the crystal structure of the title Mn(II) complex, [Mn(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Mn(II) cation is located on an inversion center and coordinated by two diethyl-nicotinamide (DENA) ligands, two 4-bromo-benzoate (PBB) anions and two water mol-ecules in a distorted octa-hedral geometry. The dihedral angle between the carboxyl-ate group and the adjacent benzene ring is 3.25 (14)°. In the mol-ecule, the pyridine ring and the benzene ring are oriented at a dihedral angle of 77.24 (5)°. In the crystal, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into a two-dimensional network. Weak inter-molecular C-H⋯O hydrogen bonds and π-π inter-actions between the pyridine rings of neighbouring mol-ecules [centroid-centroid distance = 3.537 (1) Å] further consolidate the crystal packing. |
| Starting Page | m1209 |
| Ending Page | m1210 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| PubMed reference number | 22064749 |
| DOI | 10.1107/S1600536811031412 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Volume Number | 67 |
| Alternate Webpage(s) | http://ftp.ncbi.nlm.nih.gov/pub/pmc/63/54/e-67-m1209.PMC3200634.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536811031412 |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Alkyl (C12-15) Benzoate Anions Benzoates Carboxyl Group Cations DUOXA1 gene Diethylnitrosamine Ligands Mole, unit of measurement Niacinamide Pyridines Ring device octa-arginine peptide |
| Content Type | Text |
| Resource Type | Article |
