NDLI: Enantiopure and racemic radical-cation salts of bis(2'-hydroxylpropylthio)(ethylenedithio)TTF with polyiodide anions.

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Enantiopure and racemic radical-cation salts of bis(2'-hydroxylpropylthio)(ethylenedithio)TTF with polyiodide anions.

Content Provider	Semantic Scholar
Author	Martin, Lee Wallis, John D. Guziak, Milena A. Maksymiw, Peter Konalian-Kempf, Florence Christian, Anthony Nakatsuji, Shin'ichi Yamada, Jun'ichi Akutsu, Hiroki
Copyright Year	2017
Abstract	The chiral TTF-based donor molecule bis(2'-hydroxylpropylthio)(ethylenedithio)tetrathiafulvalene (BHPT-EDT-TTF) has produced enantiopure R,R and S,S radical-cation salts with polyiodide anions I3- and I82-. Enantiomorphic 6 : 6 donor : I3 phases grown from either the R,R or S,S donor are semiconducting with similar activation energies of 0.24-0.30 eV and 0.22-0.23 eV, respectively, and contain three unique face-to-face donor pairs whose relative orientation is determined by side chain conformations and hydrogen bonding. Racemic material under the same conditions gave an insulating centrosymmetric phase with R,R and S,S donor cations in a face-to-face pair partnered with an octaiodide dianion, and with a ca. 3 : 1 disorder between the enantiomers. Enantiopure BHPT-EDT-TTF yielded two further insulating crystalline phases of composition 2 : 2 with triiodide and 2 : 1 with octaiodide.
Starting Page	4225
Ending Page	4234
Page Count	10
File Format	PDF HTM / HTML
DOI	10.1039/c6dt04645b
PubMed reference number	28280818
Journal	Medline
Volume Number	46
Issue Number	13
Alternate Webpage(s)	http://irep.ntu.ac.uk/id/eprint/30176/1/7956_Martin.pdf
Alternate Webpage(s)	http://www.rsc.org/suppdata/c6/dt/c6dt04645b/c6dt04645b1.pdf
Alternate Webpage(s)	https://doi.org/10.1039/c6dt04645b
Journal	Dalton transactions
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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