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Metallic Bi- and Monolayered Radical Cation Salts Based on Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) with the Tris(oxalato)gallate Anion
| Content Provider | Semantic Scholar |
|---|---|
| Author | Prokhorova, Tatiana G. Buravov, Lev I. Yagubskii, Eduard B. Zorina, Leokadiya V. Simonov, Sergey V. Shibaeva, Rimma P. Zverev, Vladimir N. |
| Copyright Year | 2014 |
| Abstract | New metallic triclinic (1) and monoclinic (2) crystals of the (BEDT-TTF)4AI[MIII(C2O4)3]G family of organic molecular conductors have been prepared: α-“pseudo-κ”-(BEDT-TTF)4Kx(H3O)1–x[GaIII(C2O4)3]·1,2-C6H4Br2 (x ≈ 0.45) (1) and β″-(BEDT-TTF)4Kx(H3O)1–x[GaIII(C2O4)3]·PhBr (x ≈ 0.33) (2). The triclinic crystals belong to a quite rare type of bilayered radical ion salts and contain alternating BEDT-TTF layers with two distinct packing motifs (α- and “pseudo-κ”). The monoclinic crystals contain one kind of BEDT-TTF radical cation layers. The crystal structure, transport, and magnetotransport properties of 1 and 2 have been studied. The Shubnikov–de Haas (SdH) oscillations were found in both phases. The structure and properties of 1 and 2 are compared with another similar phase with M = FeIII. |
| Starting Page | 3933 |
| Ending Page | 3940 |
| Page Count | 8 |
| File Format | PDF HTM / HTML |
| DOI | 10.1002/ejic.201400132 |
| Volume Number | 2014 |
| Alternate Webpage(s) | http://www.issp.ac.ru/lek/zverev/art78-RE.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |