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Bioinspired enantioselective synthesis of crinine-type alkaloids via iridium-catalyzed asymmetric hydrogenation of enones† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc02112g Click here for additional data file.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zuo, Xiao-Dong Guo, Shu-Min Yang, Rui Xie, Jian-Hua Zhou, Qi-Lin |
| Copyright Year | 2017 |
| Abstract | A bioinspired enantioselective synthesis of crinine-type alkaloids has been developed by iridium-catalyzed asymmetric hydrogenation of racemic cycloenones. The method features a biomimetic stereodivergent resolution of the substrates bearing a remote arylated quaternary stereocenter. Using this protocol, 24 crinine-type alkaloids and 8 analogues were synthesized in a concise and rapid way with high yield and high enantioselectivity. |
| Starting Page | 6202 |
| Ending Page | 6206 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c7sc02112g |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2017/sc/c7sc02112g |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c7/sc/c7sc02112g/c7sc02112g1.pdf |
| Alternate Webpage(s) | http://pubs.rsc.org/en/content/articlepdf/2017/sc/c7sc02112g |
| PubMed reference number | 28989653 |
| Alternate Webpage(s) | https://doi.org/10.1039/c7sc02112g |
| Journal | Medline |
| Volume Number | 8 |
| Journal | Chemical science |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
