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Selective cobalt nanoparticles for catalytic transfer hydrogenation of N-heteroarenes† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc02062g Click here for additional data file.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Chen, Feng Sahoo, Basudev Kreyenschulte, Carsten Lund, Henrik S. Zeng, Min Junge, Kathrin Beller, Matthias |
| Copyright Year | 2017 |
| Abstract | Nitrogen modified cobalt catalysts supported on carbon were prepared by pyrolysis of the mixture generated from cobalt(ii) acetate in aqueous solution of melamine or waste melamine resins, which are widely used as industrial polymers. The obtained nanostructured materials catalyze the transfer hydrogenation of N-heteroarenes with formic acid in the absence of base. The optimal Co/Melamine-2@C-700 catalyst exhibits high activity and selectivity for the dehydrogenation of formic acid into molecular hydrogen and carbon dioxide and allows for the reduction of diverse N-heteroarenes including substrates featuring sensitive functional groups. |
| Starting Page | 6239 |
| Ending Page | 6246 |
| Page Count | 8 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c7sc02062g |
| PubMed reference number | 28989657 |
| Journal | Medline |
| Volume Number | 8 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c7/sc/c7sc02062g/c7sc02062g1.pdf |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2017/sc/c7sc02062g |
| Alternate Webpage(s) | https://doi.org/10.1039/c7sc02062g |
| Journal | Chemical science |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
