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Selective syntheses of leuconolam, leuconoxine, and mersicarpine alkaloids from a common intermediate through regiocontrolled cyclizations by Staudinger reactions† †Electronic supplementary information (ESI) available: Experimental details and procedures, compound characterization data, copies of 1H
| Content Provider | Semantic Scholar |
|---|---|
| Author | Li, Zhengliang Geng, Qian Pritchett, Beau P. Baba, Katsuaki Numajiri, Yoshitaka Stoltz, Brian M. Liang, Guangxin |
| Copyright Year | 2015 |
| Abstract | Selective syntheses of leuconolam, leuconoxine, and mersicarpine alkaloids bearing distinctive core structures were achieved through Staudinger reactions using a common intermediate. In the key cyclization step, water functioned like a switch to control which core structure to produce. The chemistry allowed for selective syntheses of the group of alkaloids from a simple intermediate through straightforward chemical operations. |
| Starting Page | 236 |
| Ending Page | 240 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| PubMed reference number | 25717379 |
| Journal | Medline |
| Volume Number | 2 |
| Alternate Webpage(s) | http://stoltz2.caltech.edu/publications/166-s-2015.pdf |
| Alternate Webpage(s) | http://pubs.rsc.org/en/content/articlepdf/2015/qo/c4qo00312h?page=search |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/getauthorversionpdf/C4QO00312H |
| Alternate Webpage(s) | http://authors.library.caltech.edu/55447/2/c4qo00312h1_si.pdf |
| Alternate Webpage(s) | http://authors.library.caltech.edu/55447/1/c4qo00312h.pdf |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2015/qo/c4qo00312h |
| Alternate Webpage(s) | https://doi.org/10.1039/C4QO00312H |
| Journal | Organic chemistry frontiers : an international journal of organic chemistry |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
