NDLI: Gold(iii)–arene complexes by insertion of olefins into gold–aryl bonds† †Electronic supplementary information (ESI) available: Experimental details (syntheses, analytical data and copies of 1H, 13C and 31P NMR spectra), crystallographic data of 2 and computational details. CCDC 1526613 and 1538015.

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Gold(iii)–arene complexes by insertion of olefins into gold–aryl bonds† †Electronic supplementary information (ESI) available: Experimental details (syntheses, analytical data and copies of 1H, 13C and 31P NMR spectra), crystallographic data of 2 and computational details. CCDC 1526613 and 1538015.

Content Provider	Semantic Scholar
Author	Rekhroukh, Feriel Blons, Charlie Estévez, Laura Mallet-Ladeira, Sonia Miqueu, Karinne Amgoune, Abderrahmane Bourissou, Didier
Copyright Year	2017
Abstract	The synthesis and characterization of the first gold(iii)-arene complexes are described. Well-defined (P,C)-cyclometalated gold(iii)-aryl complexes were prepared and characterized by NMR spectroscopy. These complexes swiftly and cleanly reacted with norbornene and ethylene to provide cationic gold(iii)-alkyl complexes, in which the remote phenyl ring was η2-coordinated to gold. The interaction between the aromatic ring and the gold(iii) center was thoroughly analyzed by NMR spectroscopy, X-ray diffraction, and DFT calculations. The π-arene coordination was found to significantly influence the stability and reactivity of low coordinated gold(iii) alkyl species.
Starting Page	4539
Ending Page	4545
Page Count	7
File Format	PDF HTM / HTML
DOI	10.1039/c7sc00145b
Alternate Webpage(s)	http://www.rsc.org/suppdata/c7/sc/c7sc00145b/c7sc00145b1.pdf
PubMed reference number	28660067
Alternate Webpage(s)	https://doi.org/10.1039/c7sc00145b
Journal	Medline
Volume Number	8
Journal	Chemical science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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