NDLI: Cellulose-supported chiral rhodium nanoparticles as sustainable heterogeneous catalysts for asymmetric carbon–carbon bond-forming reactions† †Electronic supplementary information (ESI) available: General procedures, materials, and instrumentation; synthesis, characterization and relevant spectra/cha

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Cellulose-supported chiral rhodium nanoparticles as sustainable heterogeneous catalysts for asymmetric carbon–carbon bond-forming reactions† †Electronic supplementary information (ESI) available: General procedures, materials, and instrumentation; synthesis, characterization and relevant spectra/cha

Content Provider	Semantic Scholar
Author	Yasukawa, Tomohiro Miyamura, Hiroyuki Kobayashi, Shū
Copyright Year	2015
Abstract	Cellulose-supported chiral Rh nanoparticle (NP) catalysts have been developed. The Rh NPs, which were well dispersed on cellulose, catalyzed the asymmetric 1,4-addition of arylboronic acids to enones and enoates, one of the representative asymmetric carbon–carbon bond-forming reactions, in the presence of chiral diene ligands, providing the corresponding adducts in high yields with outstanding enantioselectivities without metal leaching. The solid-state NMR analysis of the chiral NP system directly suggested interactions between the Rh NPs and the chiral ligand on cellulose. This is the first example of using polysaccharide-supported chiral metal nanoparticles for asymmetric carbon–carbon bondforming reactions.
Starting Page	6224
Ending Page	6229
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1002/chin.201609064
PubMed reference number	30090239
Volume Number	6
Alternate Webpage(s)	https://pubs.rsc.org/en/content/getauthorversionpdf/C5SC02510A
Alternate Webpage(s)	https://pubs.rsc.org/en/content/articlepdf/2015/sc/c5sc02510a
Alternate Webpage(s)	https://doi.org/10.1002/chin.201609064
Journal	Chemical Science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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