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Diastereodivergent organocatalysis for the asymmetric synthesis of chiral annulated furans† †Electronic supplementary information (ESI) available: Complete experimental procedures and full compound characterisation, including HPLC traces and NMR spectra (PDF). CCDC 1046068 and 1046069. For ESI and c
| Content Provider | Semantic Scholar |
|---|---|
| Author | Verrier, Charlie Melchiorre, Paolo |
| Copyright Year | 2015 |
| Abstract | Chiral 2,3-furan fused carbocycles bearing adjacent quarternary and tertiary carbon stereocenters are selectively synthesized by asymmetric addition of β-ketoesters to 2-(1-alkynyl)-2-alkene-1-ones catalyzed by natural cinchona alkaloids followed by a silver-catalyzed intramolecular cycloisomerization. |
| Starting Page | 4242 |
| Ending Page | 4246 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| DOI | 10.1002/chin.201543115 |
| PubMed reference number | 29218190 |
| Volume Number | 6 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c5/sc/c5sc01052g/c5sc01052g1.pdf |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2015/sc/c5sc01052g |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/getauthorversionpdf/C5SC01052G |
| Alternate Webpage(s) | https://doi.org/10.1002/chin.201543115 |
| Journal | Chemical Science |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |