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Carboxylate-directed C–H allylation with allyl alcohols or ethers† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc01741g
| Content Provider | Semantic Scholar |
|---|---|
| Author | Hu, Xiao-Qiang Hu, Zhiyong Trita, Andrada Stefania Zhang, Guodong Goossen, Lukas J. |
| Copyright Year | 2018 |
| Abstract | A [Ru(p-cymene)Cl2]2 catalyst activates allyl alcohols and ethers for the regioselective ortho-C-H allylation of aromatic and heteroaromatic carboxylates. The reaction is orthogonal to most C-H functionalisations with allyl alcohols in that allyl arenes rather than carbonyl compounds are obtained. A wide range of substrates are thus smoothly transformed to allylarenes at 50 °C in phosphate-buffered 2,2,2-trichloroethanol. The reaction concept combines the use of abundant reagents and directing groups in a sustainable, waste-minimised method for C-C bond formation. |
| Starting Page | 5289 |
| Ending Page | 5294 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c8sc01741g |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c8/sc/c8sc01741g/c8sc01741g1.pdf |
| PubMed reference number | 29997885 |
| Alternate Webpage(s) | https://doi.org/10.1039/c8sc01741g |
| Journal | Medline |
| Volume Number | 9 |
| Journal | Chemical science |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
