NDLI: Oxidative β-C–H sulfonylation of cyclic amines† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc04900e

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Oxidative β-C–H sulfonylation of cyclic amines† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc04900e

Content Provider	Semantic Scholar
Author	Griffiths, R. J. Kong, Wenhui Richards, Stephen A. Burley, Glenn A. Willis, Michael C. Talbot, Eric P. A.
Copyright Year	2018
Abstract	A transition metal-free strategy for the dehydrogenative b-sulfonylation of tertiary cyclic amines is described. N-Iodosuccinimide facilitates regioselective oxidative sulfonylation at C–H bonds positioned b to the nitrogen atom of tertiary amines, installing enaminyl sulfone functionality in cyclic systems. Mild reaction conditions, broad functional group tolerance and a wide substrate scope are demonstrated. The nucleophilic character of the enaminyl sulfone is harnessed, demonstrating potential application for scaffold diversification.
Starting Page	2295
Ending Page	2300
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1039/c7sc04900e
PubMed reference number	29719703
Volume Number	9
Alternate Webpage(s)	https://strathprints.strath.ac.uk/63142/1/Griffiths_etal_CS_2018_Oxidative_B_C_H_sulfonylation_of_cyclic.pdf
Alternate Webpage(s)	https://ftp.ncbi.nlm.nih.gov/pub/pmc/oa_pdf/80/2d/SC-009-C7SC04900E.PMC5897885.pdf
Alternate Webpage(s)	https://doi.org/10.1039/c7sc04900e
Journal	Chemical Science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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