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Rhodium-catalyzed enantio- and diastereoselective intramolecular [2 + 2 + 2] cycloaddition of unsymmetrical dienynes.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Sagae, Hiromi Noguchi, Keiichi Hirano, Masao Tanaka, Ken |
| Copyright Year | 2008 |
| Abstract | A cationic rhodium(i)/(R)-H(8)-BINAP or (R)-Segphos complex catalyzes an intramolecular [2 + 2 + 2] cycloaddition of unsymmetrical dienynes, leading to fused tri- and tetracyclic cyclohexenes bearing two tertiary or quaternary carbon centers in high yields with high enantio- and diastereoselectivity. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/b804294b |
| PubMed reference number | 18685783 |
| Journal | Medline |
| Volume Number | 32 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/cc/b8/b804294b/b804294b.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/b804294b |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |