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Ruthenium catalyzed remote C4-selective C-H functionalisation of carbazoles via σ-activation.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Leitch, Jamie A. Heron, Callum J. McKnight, Janette Kociok-Köhn, Gabriele Bhonoah, Yunas Frost, Christopher G. |
| Copyright Year | 2017 |
| Abstract | We report the C4-selective C-H alkylation of carbazole derivatives furnished with a pyrimidine directing group at N9. This was realized using ruthenium catalyzed σ-activation methodology, whereby C-H activation at C1 enables the interaction of this ruthenacycle, at the para position to the metal center, with tertiary alkyl radicals. |
| Starting Page | 13039 |
| Ending Page | 13042 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c7cc07606a |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2017/cc/c7cc07606a |
| Alternate Webpage(s) | https://purehost.bath.ac.uk/ws/portalfiles/portal/159887102/Final_Manuscript.pdf |
| PubMed reference number | 29164185 |
| Alternate Webpage(s) | https://doi.org/10.1039/c7cc07606a |
| Journal | Medline |
| Volume Number | 53 |
| Issue Number | 97 |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |