NDLI: 1-Naphthylamine functionalized Pt nanoparticles: electrochemical activity and redox chemistry occurring on one surface

Please wait, while we are loading the content...

1-Naphthylamine functionalized Pt nanoparticles: electrochemical activity and redox chemistry occurring on one surface

Content Provider	Semantic Scholar
Author	Morsbach, Eva Nesselberger, Markus Warneke, Jonas Harz, Philipp Arenz, Matthias Bäumer, Marcus Kunz, Sebastian
Copyright Year	2015
Abstract	We present the preparation and electrochemical application of Pt nanoparticles (Pt NPs) functionalized with 1-naphthylamine. Under electrochemical conditions, Pt surface bound 1-naphthylamine (NA) can be reversibly switched (oxidized and reduced), while simultaneously electrocatalytic reactions (e.g. CO oxidation) can proceed on the Pt surface. While the redox activity of the ligand is established immediately after functionalization, the functionalized NPs have to be stored as a colloidal dispersion in tetrahydrofuran (THF) prior to deposition onto the support material in order to induce their catalytic activity. We interpret this catalytic activation due to partial desorption of ligands from the particle surface induced by storing the particles in THF. However, the experimental results do not indicate a loss of ligands from the ligand shell, but evidence that the ligands form oligomers when kept as colloids in THF. As a result the catalytic surface becomes partially available while the redox activity of the ligands is maintained.
Starting Page	2557
Ending Page	2564
Page Count	8
File Format	PDF HTM / HTML
DOI	10.1039/C4NJ02040E
Alternate Webpage(s)	http://www.rsc.org/suppdata/nj/c4/c4nj02040e/c4nj02040e1.pdf
Alternate Webpage(s)	https://doi.org/10.1039/C4NJ02040E
Volume Number	39
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

Central Library (ISO-9001:2015 Certified)
Indian Institute of Technology Kharagpur
Kharagpur, West Bengal, India | PIN - 721302

See location in the Map
03222 282435
Mail: support@ndl.gov.in

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in