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Bis(N-sec-butyl-N-n-propyldithiocarbamato-κ2 S,S′)(1,10-phenanthroline-κ2 N,N′)zinc(II)
| Content Provider | Semantic Scholar |
|---|---|
| Author | Alzaalouk, Amna Salem Baba, Ibrahim Tahir, Mohamed Ibrahim Mohamed Ng, Seik Weng Tiekink, Edward R. T. |
| Copyright Year | 2010 |
| Abstract | Two independent but very similar mol-ecules comprise the asymmetric unit of the title compound, [Zn(C(8)H(16)NS(2))(2)(C(12)H(8)N(2))]. The N(2)S(4) donor set about Zn is defined by two symmetrically chelating dithio-carbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octa-hedral coordination geometry arise from the restricted bite angles of the ligands. The main feature of the crystal packing is the formation of tetra-meric supra-molecular aggregates mediated by C-H⋯S inter-actions. Disorder was found in each of the sec-butyl groups. This was resolved over two positions in each case with the major components of the disorder having site occupancies in the range 0.551 (6)-0.725 (5). |
| Starting Page | m1165 |
| Ending Page | m1166 |
| Page Count | 2 |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S1600536810033672 |
| PubMed reference number | 21588557 |
| Journal | Medline |
| Volume Number | 66 |
| Alternate Webpage(s) | http://ftp.ncbi.nlm.nih.gov/pub/pmc/59/43/e-66-m1165.PMC3008025.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536810033672 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
