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Bis(3,4-dimethoxybenzoato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)copper(II)
| Content Provider | Semantic Scholar |
|---|---|
| Author | Liu, Yaru Sun, Junshan Niu, Xiaoli |
| Copyright Year | 2009 |
| Abstract | The asymmetric unit of the title compound, [Cu(C(9)H(9)O(4))(2)(C(12)H(8)N(2))], contains one half-mol-ecule, the complete mol-ecule being generated by a twofold rotation axis. The Cu(II) atom exhibits a six-coordinated distorted octa-hedral geometry with two N atoms from the phenanthroline ligand [Cu-N 2.007 (2) Å] and four O atoms from two 3,4-dimethoxy-benzoate ligands [Cu-O 1.950 (1) and 2.524 (1) Å]. The difference in Cu-O bond distances indicates a strong Jahn-Teller effect. In the crystal, C-H⋯π inter-actions result in chains of mol-ecules along the c axis. |
| Starting Page | m34 |
| Ending Page | m34 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S1600536809052234 |
| PubMed reference number | 21579933 |
| Journal | Medline |
| Volume Number | 66 |
| Alternate Webpage(s) | http://ftp.ncbi.nlm.nih.gov/pub/pmc/51/0a/e-66-00m34.PMC2980123.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536809052234 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
