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catena-Poly[[(1,10-phenanthroline-κ2 N,N′)lead(II)]-di-μ-nitrato-κ3 O,O′:O′′;κ3 O:O′,O′′-[(1,10-phenanthroline-κ2 N,N′)lead(II)]-bis(μ-2,2,2-trichloroacetato-κ2 O:O′)]
| Content Provider | Semantic Scholar |
|---|---|
| Author | Shahverdizadeh, Gholam Hossein Ng, Seik Weng Tiekink, Edward R. T. Mirtamizdoust, Babak |
| Copyright Year | 2012 |
| Abstract | In the title Pb(II) complex, [Pb(2)(C(2)Cl(3)O(2))(2)(NO(3))(2)(C(12)H(8)N(2))(2)](n), the 1,10-phenanthroline ligand is chelating, the nitrate anion chelates one Pb(II) ion and simultaneously bridges a neighbouring Pb(II) ion via the third O atom, and the trichloro-acetate anion is bidentate, bridging two Pb(II) ions. The coordination geometry is based on a penta-gonal-bipramidal geometry defined by an N(2)O(5) donor set with no obvious stereochemical role for the lead-bound lone pair of electrons. The coordination polymer has a zigzag topology along [010] and comprises alternating eight-membered {PbONO}(2) and {PbOCO}(2) rings. |
| Starting Page | m237 |
| Ending Page | m238 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| PubMed reference number | 22412401v1 |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536812003595 |
| DOI | 10.1107/S1600536812003595 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Volume Number | 68 |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | 1,10-phenanthroline Acetate Anatomy, Regional Anions Chelating Activity Chelating Agents Electrons Ions Ligands Nitrates Pb2+ Polymers Ring device Second trimester penta maternal screen:Imp:Pt:Ser/Plas:Nom |
| Content Type | Text |
| Resource Type | Article |
