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Di-μ-benzoato-κ3 O,O′:O;κ3 O:O,O′-bis[(benzoato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)lead(II)]
| Content Provider | Semantic Scholar |
|---|---|
| Author | Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong |
| Copyright Year | 2011 |
| Abstract | In the centrosymmetric dinuclear title compound, [Pb(2)(C(7)H(5)O(2))(4)(C(12)H(8)N(2))(2)], two Pb(2+) ions are connected by two tridentate bridging benzoate anions. The Pb(2+) ion is seven-coordinated by five O atoms from three benzoate anions and two N atoms from the 1,10-phenanthroline ligands. The benzoate anions adopt two different coordination modes, one bidentate-chelating and one tridentate bridging-chelating. The three-dimensional supra-molecular framework is achieved by inter-molecular π-π stacking inter-actions, with a shortest centroid-centroid distance of 3.617 (4) Å. |
| Starting Page | m778 |
| Ending Page | m778 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S160053681101840X |
| PubMed reference number | 21754661 |
| Journal | Medline |
| Volume Number | 67 |
| Alternate Webpage(s) | https://doi.org/10.1107/S160053681101840X |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |