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Gas-chromatographic determination of the enantiomeric composition of optically active alcohols and amines using achiral bifunctional reagents
| Content Provider | Semantic Scholar |
|---|---|
| Author | Stankov, Ivan Sitnikov, Vitali Sadovnikov, Sergey V. Sergeeva, A. A. Derevyagina, I. D. Morozova, Oksana Mylova, S. N. Kuzmina, Natalya E. Gurenko, N. K. |
| Copyright Year | 2005 |
| Abstract | A technique for determining the enantiomeric composition of 2-octanol and α-phenylethylamine with the use of gas chromatography on optically inactive stationary phases is proposed. The technique is based on the formation of symmetrical diastereomeric derivatives upon the interaction of enantiomers with bifunctional achiral reagents: dimethyldichlorosilane, bromochloromethane, and dibromoethane. The reagents were chosen from the viewpoint of the synthesis of diastereomers with a minimum distance between the chiral centers. This minimum distance is responsible for a difference in the energies of interaction of the derivatives with the stationary liquid phase, which is sufficient for the separation of these derivatives. |
| Starting Page | 264 |
| Ending Page | 273 |
| Page Count | 10 |
| File Format | PDF HTM / HTML |
| DOI | 10.1007/s10809-005-0083-0 |
| Volume Number | 60 |
| Alternate Webpage(s) | https://page-one.springer.com/pdf/preview/10.1007/s10809-005-0083-0 |
| Alternate Webpage(s) | https://doi.org/10.1007/s10809-005-0083-0 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
