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Synthesis of optically active bifunctional building blocks through enantioselective copper-catalyzed allylic alkylation using Grignard reagents.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zijl, Anthoni W. Van López, Fernando Juárez Minnaard, Adriaan J. Feringa, Ben L. |
| Copyright Year | 2007 |
| Abstract | Enantioselective copper-catalyzed allylic alkylations were performed on allylic bromides with a protected hydroxyl or amine functional group using several Grignard reagents and Taniaphos L1 as a ligand. The terminal olefin moiety in the products was transformed into various functional groups without racemization, providing facile access to a variety of versatile bifunctional chiral building blocks. |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/jo0625655 |
| Alternate Webpage(s) | https://core.ac.uk/download/pdf/12906765.pdf |
| PubMed reference number | 17343420 |
| Alternate Webpage(s) | https://doi.org/10.1021/jo0625655 |
| Journal | Medline |
| Volume Number | 72 |
| Issue Number | 7 |
| Journal | The Journal of organic chemistry |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
