NDLI: A flexible approach to Pd-catalyzed carbonylations via aroyl dimethylaminopyridinium salts† †Electronic supplementary information (ESI) available: Experimental procedures, characterization data, and NMR spectra for compounds. See DOI: 10.1039/c5sc02949j

Please wait, while we are loading the content...

A flexible approach to Pd-catalyzed carbonylations via aroyl dimethylaminopyridinium salts† †Electronic supplementary information (ESI) available: Experimental procedures, characterization data, and NMR spectra for compounds. See DOI: 10.1039/c5sc02949j

Content Provider	Semantic Scholar
Author	Quesnel, Jeffrey S. Fabrikant, Alexander Arndtsen, Bruce A.
Copyright Year	2016
Abstract	4-Dimethylaminopyridine (DMAP) is shown to undergo Pd/P t Bu3 catalyzed coupling with aryl halides and carbon monoxide to form electrophilic aroyl-DMAP salts. The reaction is easily scalable to prepare multigram quantities with low catalyst loadings, while the precipitation of these salts as they form leads to products with low impurities. These reagents rapidly react with a variety of nucleophiles, including those that contain potentially incompatible functional groups under standard carbonylative conditions.
Starting Page	295
Ending Page	300
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1039/c5sc02949j
PubMed reference number	29861983
Journal	Medline
Volume Number	7
Alternate Webpage(s)	http://www.rsc.org/suppdata/c5/sc/c5sc02949j/c5sc02949j1.pdf
Alternate Webpage(s)	https://pubs.rsc.org/en/content/getauthorversionpdf/C5SC02949J
Alternate Webpage(s)	https://pubs.rsc.org/en/content/articlepdf/2016/sc/c5sc02949j
Alternate Webpage(s)	http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC02949J
Alternate Webpage(s)	https://ftp.ncbi.nlm.nih.gov/pub/pmc/oa_pdf/c3/67/SC-007-C5SC02949J.PMC5952522.pdf
Alternate Webpage(s)	https://doi.org/10.1039/c5sc02949j
Journal	Chemical science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in