NDLI: A robust ALD-protected silicon-based hybrid photoelectrode for hydrogen evolution under aqueous conditions† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc05006f

Please wait, while we are loading the content...

A robust ALD-protected silicon-based hybrid photoelectrode for hydrogen evolution under aqueous conditions† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc05006f

Content Provider	Semantic Scholar
Author	Chandrasekaran, Soundarrajan Kaeffer, Nicolas Cagnon, Laurent Aldakov, Dmitry Fize, Jennifer Nonglaton, Guillaume Baleras, F. Mailley, Pascal Artero, Vincent
Copyright Year	2019
Abstract	Hydrogen production through direct sunlight-driven water splitting in photo-electrochemical cells (PECs) is a promising solution for energy sourcing. PECs need to fulfill three criteria: sustainability, cost-effectiveness and stability. Here we report an efficient and stable photocathode platform for H2 evolution based on Earth-abundant elements. A p-type silicon surface was protected by atomic layer deposition (ALD) with a 15 nm TiO2 layer, on top of which a 300 nm mesoporous TiO2 layer was spin-coated. The cobalt diimine-dioxime molecular catalyst was covalently grafted onto TiO2 through phosphonate anchors and an additional 0.2 nm ALD-TiO2 layer was applied for stabilization. This assembly catalyzes water reduction into H2 in phosphate buffer (pH 7) with an onset potential of +0.47 V vs. RHE. The resulting current density is -1.3 ± 0.1 mA cm-2 at 0 V vs. RHE under AM 1.5 solar irradiation, corresponding to a turnover number of 260 per hour of operation and a turnover frequency of 0.071 s-1.
Starting Page	4469
Ending Page	4475
Page Count	7
File Format	PDF HTM / HTML
DOI	10.1039/C8SC05006F
PubMed reference number	31057774
Journal	Medline
Volume Number	10
Alternate Webpage(s)	http://www.rsc.org/suppdata/c8/sc/c8sc05006f/c8sc05006f1.pdf
Alternate Webpage(s)	https://ftp.ncbi.nlm.nih.gov/pub/pmc/oa_pdf/a4/5f/SC-010-C8SC05006F.PMC6482884.pdf
Alternate Webpage(s)	https://doi.org/10.1039/C8SC05006F
Journal	Chemical science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

A robust ALD-protected silicon-based hybrid photoelectrode for hydrogen evolution under aqueous conditions.

Sustainable ppm level palladium-catalyzed aminations in nanoreactors under mild, aqueous conditions† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc03710a

A practical, organic-mediated, hybrid electrolyser that decouples hydrogen production at high current densities† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc05388f

Photoinduced oxidative activation of electron-rich arenes: alkenylation with H2 evolution under external oxidant-free conditions† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc04634k

Silylated cyclopentadienes as competent silicon Lewis acid catalysts† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc02279h

UbFluor: a mechanism-based probe for HECT E3 ligases† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc01167e

A water-processable cellulose-based resist for advanced nanofabrication† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8nr04851g

A robust iron catalyst for the selective hydrogenation of substituted (iso)quinolones† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc02744g

Mechanism of hydrogen peroxide formation by lytic polysaccharide monooxygenase† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc03980a

A robust ALD-protected silicon-based hybrid photoelectrode for hydrogen evolution under aqueous conditions† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc05006f

Similar Documents

A robust ALD-protected silicon-based hybrid photoelectrode for hydrogen evolution under aqueous conditions.

Sustainable ppm level palladium-catalyzed aminations in nanoreactors under mild, aqueous conditions† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc03710a

A practical, organic-mediated, hybrid electrolyser that decouples hydrogen production at high current densities† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc05388f

Photoinduced oxidative activation of electron-rich arenes: alkenylation with H2 evolution under external oxidant-free conditions† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc04634k

Silylated cyclopentadienes as competent silicon Lewis acid catalysts† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc02279h

UbFluor: a mechanism-based probe for HECT E3 ligases† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc01167e

A water-processable cellulose-based resist for advanced nanofabrication† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8nr04851g

A robust iron catalyst for the selective hydrogenation of substituted (iso)quinolones† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc02744g

Mechanism of hydrogen peroxide formation by lytic polysaccharide monooxygenase† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc03980a

A robust ALD-protected silicon-based hybrid photoelectrode for hydrogen evolution under aqueous conditions† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc05006f