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Enantioselective syn-selective scandium-catalyzed ene reactions.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Evans, David A. Wu, Jimmy |
| Copyright Year | 2005 |
| Abstract | An enantio- and diastereoselective carbonyl-ene reaction catalyzed by chiral scandium pyridyl bis(oxazoline) (pybox) complexes has been developed. Uniformly high enantiomeric excesses and good yields were observed. Use of trisubstituted olefins generated the syn product in high enantio- and diastereoselectivity. |
| Starting Page | 1538 |
| Ending Page | 1538 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://evans.rc.fas.harvard.edu/pdf/evans296.pdf |
| PubMed reference number | 15926812v1 |
| Volume Number | 127 |
| Issue Number | 22 |
| Journal | Journal of the American Chemical Society |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Alkenes Carbonyl Cyanide p-Trifluoromethoxyphenylhydrazone Iron Overload Scandium |
| Content Type | Text |
| Resource Type | Article |