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Non Deprotonated Metal Complexes of the Bis-amide Tetradentate Ligand N,N′ -(Dipicolyl) -1,8-naphthylenediamine
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zafiropoulos, Th. F. Perlepes, Spiros P. Ioannou, Panayiotis V. Tsangaris, John M. Galinos, Andreas G. |
| Copyright Year | 1981 |
| Abstract | Abstract Complexes of the general formula M(LH2)Cl2 · 2 H2O, where LH2 = N,N′-(dipicolyl)-1,8-naphthylenediamine and M = Mn, Ni and Cu, have been prepared. None of the metal ions used promote amide deprotonation on coordination: LH2 acts as a tetradentate ligand. Distorted octahedral stereochemistries for the complexes in the solid state have been proposed utilising microanalyses, magnetic susceptibilities, molar conductance measurements and IR and visible spectral data. The Ni(II) complex exhibits evidence of a polymeric structure. |
| Starting Page | 87 |
| Ending Page | 93 |
| Page Count | 7 |
| File Format | PDF HTM / HTML |
| DOI | 10.1515/znb-1981-0119 |
| Volume Number | 36 |
| Alternate Webpage(s) | http://zfn.mpdl.mpg.de/data/Reihe_B/36/ZNB-1981-36b-0087.pdf |
| Alternate Webpage(s) | https://doi.org/10.1515/znb-1981-0119 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |