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Darstellung und Kristallstruktur des Bis(2-amino-1-ammonioethan)hexasulfids [H3N-(CH2)2-NH2]2S6 /Synthesis and Crystal Structure of Bis(2-amino-1-ammonioethan)hexasulfide, [H3N—(CH2)2-NH2]2S6
| Content Provider | Semantic Scholar |
|---|---|
| Author | Boettcher, Peter Hermanns, H. Buchkremer‐ |
| Copyright Year | 1987 |
| Abstract | Bis(2-amino-1-ammonioethan)hexasulfide has been synthesized from ethylendiamine, sulfur and hydrogensulfide in ethanolic solution. It consists of unbranched chains S62- (helical all-trans-conformation) and monoprotonated ethylenediamine cations; the latter show the uncommon synclinical conformation. A remarkable system of N - H···S-bridges links the S62-chains to form an infinite array. It crystallizes in the space group P1̄ with a = 9.203(4) Å, b = 9.921(4) Å, c = 15.583(5) Å, α = 93.03(3)°, β = 90.04(3)°, γ = 79.07(3)° |
| Starting Page | 267 |
| Ending Page | 271 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| DOI | 10.1515/znb-1987-0303 |
| Alternate Webpage(s) | http://zfn.mpdl.mpg.de/data/Reihe_B/42/ZNB-1987-42b-0267.pdf |
| Alternate Webpage(s) | https://doi.org/10.1515/znb-1987-0303 |
| Volume Number | 42 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |