NDLI: Spezielle Alkylammoniumhexachlorometallate, II [1] Synthese und Kristallstruktur von Bis(1,2-diammoniopropan)hexachlororhodat(III)-chlorid, [H3N-CH(CH3)-CH2-NH3]2[RhCl6]Cl/ Alkylammonium Hexachlorometallates, II [1] Synthesis, and Crystal Structure of Bis(1,2-diammoniopropane) Hexachlororhodate(III) Chloride, (H3N-CH(CH3)-CH2-NH3]-[RhCl6]Cl

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Spezielle Alkylammoniumhexachlorometallate, II [1] Synthese und Kristallstruktur von Bis(1,2-diammoniopropan)hexachlororhodat(III)-chlorid, [H3N-CH(CH3)-CH2-NH3]2[RhCl6]Cl/ Alkylammonium Hexachlorometallates, II [1] Synthesis, and Crystal Structure of Bis(1,2-diammoniopropane) Hexachlororhodate(III) Chloride, (H3N-CH(CH3)-CH2-NH3]-[RhCl6]Cl

Content Provider	Scilit
Author	Frank, Walter Reiß, Guido J.
Copyright Year	1996
Abstract	Bis(1,2-diammoniopropane) hexachlororhodate(III) chloride, [H₃N-CH(CH₃)-CH₂-NH₃]₂ [RhCl₆]Cl (1) has been obtained by the reaction of rhodium(III) chloride with rac-1,2- diammoniopropane dihydrochloride in hydrochloric acid solution. The quasi-ternary compound, which crystallizes in the orthorhombic space group Pbca (a - 11.0007(13) Å, b = 22.181(2) A, c = 14.638(2) A, V = 3571.7(7) Å³, \ T = -120 °C, Z - 8) contains two crystallographically independent 1,2-diammoniopropane ions beside one hexachlororhodate and one chloride ion. One of the cations shows a R/S-S/R-disorder of enantiomeric pairs in the centrosymmetric crystal lattice. The packing scheme is determined by a complex framework of hydrogen bonds.
Related Links	http://www.degruyter.com/downloadpdf/j/znb.1996.51.issue-10/znb-1996-1016/znb-1996-1016.xml
Ending Page	1463
Page Count	5
Starting Page	1459
ISSN	09320776
e-ISSN	18657117
DOI	10.1515/znb-1996-1016
Journal	Zeitschrift für Naturforschung B
Issue Number	10
Volume Number	51
Language	English
Publisher	Walter de Gruyter GmbH
Publisher Date	1996-10-01
Access Restriction	Open
Subject Keyword	Zeitschrift Für Naturforschung B Inorganic Chemistry Hexachlororhodate Alkylammonium Salt Crystal Structure Hydrogen Bonding Journal: Zeitschrift für Naturforschung B, Issue- 2
Content Type	Text
Resource Type	Article
Subject	Chemistry

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