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Estimating slow-motional rotational correlation times for nitroxides by electron spin resonance
| Content Provider | Semantic Scholar |
|---|---|
| Author | Goldman, Steven A. Bruno, Gerald V. Freed, Jack H. |
| Copyright Year | 1972 |
| Abstract | A simple method of estimating slow-motional rotational correlation times rR for nitroxides by esr, which is based on the rigorous theory of Freed, Bruno, and Polnaszek, is discussed. The results can be fit to the expression r3 = a(1 S)b , where S is the ratio of the separation of the outer hyperfine extrema to that for t,he rigid limit value. The parameters a and b depend upon intrinsic line width, rotational model, and hyperfine parameters, and appropriate results are given. |
| Starting Page | 1858 |
| Ending Page | 1860 |
| Page Count | 3 |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/j100657a013 |
| Volume Number | 76 |
| Alternate Webpage(s) | https://www.acert.cornell.edu/PDFs/JPhysChem76_1858_1972.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
