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Characterization of the ( D 2 O ) 2 Hydrogen-Bond-Acceptor Antisymmetric Stretch by IR Cavity Ringdown Laser Absorption Spectroscopy
| Content Provider | Semantic Scholar |
|---|---|
| Author | Paul, Joseph B. Provencal, Robert Allen Saykally, Richard J. |
| Copyright Year | 1998 |
| Abstract | The IR-CRLAS technique has been used to measure the mid-infrared O-D stretching spectrum of the fully deuterated gas-phase water dimer for the first time. The instrumentally limited resolution of 1 GHz resolves the acceptor tunneling splittings and the rotational line manifolds. The analysis of these splittings exploits the local nature of the excitation and yields a description of the acceptor tunneling motion that supports previous experimental and theoretical results. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://www.cchem.berkeley.edu/rjsgrp/publications/papers/1998/206_paul_1998.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |