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Infrared Cavity Ringdown Laser Absorption Spectroscopy (IR-CRLAS) of jet-cooled water clusters
| Content Provider | Semantic Scholar |
|---|---|
| Author | Paul, Joseph B. Collier, C. Patrick Saykally, Richard J. Scherer, James Joseph |
| Copyright Year | 1995 |
| Abstract | The authors have recently extended the Cavity Ringdown Laser Absorption Spectroscopy technique into the infrared. Studies in the 3.0 {mu}M region of water clusters in molecular jets have found two vibrationally resolved bands centered at 3356 {+-}1 cm{sup -1} and 3400 {+-}3 cm{sup -1}, which have been previously assigned to the water pentamer and tetramer, respectively. Additionally, the authors observe a broad continuum absorption exhibiting long range structure, attributable to an inhomogeneously broadened OH-stretch excitation in large water clusters. This feature exhibits similarities with spectra of large water polymers found in cryogenic matrices, and with the infrared absorption of bulk amorphous ice. |
| File Format | PDF HTM / HTML |
| DOI | 10.1016/0009-2614(95)00969-B |
| Alternate Webpage(s) | http://www.cchem.berkeley.edu/rjsgrp/publications/papers/1995-1996/174_scherer.pdf |
| Alternate Webpage(s) | https://doi.org/10.1016/0009-2614%2895%2900969-B |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
