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Direct patterning of a cyclotriveratrylene derivative for directed self-assembly of C60.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Osner, Zachary Richard Nyamjav, Dorjderem Holz, Richard C. Becker, Daniel P. |
| Copyright Year | 2011 |
| Abstract | A novel apex-modified cyclotriveratrylene (CTV) derivative with an attached thiolane-containing lipoic acid linker was directly patterned onto gold substrates via dip-pen nanolithography (DPN). The addition of a dithiolane-containing linker to the apex of CTV provides a molecule that can adhere to a gold surface with its bowl-shaped cavity directed away from the surface, thereby providing a surface-bound CTV host that can be used for the directed assembly of guest molecules. Subsequent exposure of these CTV microarrays to C60 in toluene resulted in the directed assembly of predesigned, spatially controlled, high-density microarrays of C60. The molecular recognition capabilities of this CTV template toward C60 provides proof-of-concept that supramolecular CTV scaffolds can be directly patterned onto surfaces providing a foundation for the development of organic electronic and optoelectronic materials. |
| Starting Page | 275611 |
| Ending Page | 275611 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://ecommons.luc.edu/cgi/viewcontent.cgi?article=1036&context=chemistry_facpubs |
| PubMed reference number | 21613686v1 |
| Alternate Webpage(s) | https://doi.org/10.1088/0957-4484/22/27/275611 |
| DOI | 10.1088/0957-4484/22/27/275611 |
| Journal | Nanotechnology |
| Volume Number | 22 |
| Issue Number | 27 |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | APEX1 protein, human Body cavities Clinical Target Volume Clinical Use Template Iodine 10 MG/ML Topical Solution Nanolithography Nicotinamide adenine dinucleotide (NAD) Thioctic Acid Toluene cyclotriveratrylene |
| Content Type | Text |
| Resource Type | Article |
