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Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units
| Content Provider | Semantic Scholar |
|---|---|
| Author | Cheplakova, Anastasia M. Kovalenko, Konstantin A. Samsonenko, Denis G. Vinogradov, Andrey S. Karpov, Victor M. Platonov, Vyacheslav E. Fedin, Vladimir P. |
| Copyright Year | 2019 |
| Abstract | We present a series of six novel Zn(II) complexes containing anions of perfluorinated biphenyl-4,4′-dicarboxylate (oFBPDC2−). Among them are the 0D complex [Zn(eg)3](oFBPDC) (eg = ethylene glycol), the 1D [Zn(H2O)(ur)(oFBPDC)] (ur = urotropine) and [Zn(CH3OH)2(CH3OCH2CH2OH)(oFBPDC)] and the 2D layered [Zn2(CH3CN)2(oFBPDC)2]·2C6H6·2CH3CN, [Zn2(H2O)2(oFBPDC)2]·4(CH3)2CO, [{Zn4(μ3-OCH3)4}(CH3OH)4(oFBPDC)2]·[{Zn4(μ3-OCH3)4}(H2O)(CH3OH)3(oFBPDC)2]·13CH3OH. The latter coordination polymer is built up by unique Zn4(OCH3)4 cuboidal units. The complexes are characterized by single-crystal X-ray diffraction, FT-IR, elemental analysis, and TGA. Investigation of the CO2 adsorption at 195 K on [Zn2(CH3CN)2(oFBPDC)2] and [Zn2(H2O)2(oFBPDC)2] of the layered polymeric structure revealed that they have BET surface areas of 334.8 and 150.6 m2 g−1, respectively. |
| Starting Page | 2524 |
| Ending Page | 2533 |
| Page Count | 10 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C9CE00073A |
| Volume Number | 21 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c9/ce/c9ce00073a/c9ce00073a1.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
