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Dicarboxylate-bridged Mo2 paddle-wheel complexes as building units for supramolecular coordination polymers
| Content Provider | Semantic Scholar |
|---|---|
| Author | Köberl, Mathias |
| Copyright Year | 2012 |
| Abstract | Treatment of [Mo2(L)10][BF4]4 (L = CH3CN) with dicarboxylates in acetonitrile led to several dicarboxylate-bridged macromolecules. By using perfluoroterephthalate and isophthalates (m-bdc-X), square-shaped complex [(L)6Mo2(O2C–C6F4–CO2)]4[BF4]8 and bowl-shaped triangles [(L)6Mo2(m-bdc–X)]3[BF4]6 (X = OH, Br, NH2) were synthesized. Synthesis of 1D and 3D coordination polymers via assembly of molecular building blocks is possible. 1D polymer {[(CH3CH2CN)6Mo2(O2C–C6F4–CO2)]4[BF4]8}n is composed of square-shaped building blocks axially connected via BF4 anions. Hexagonal array of triangular building blocks via intermolecular H-F interactions leads to 3D polymer {[(L)6Mo2(m-bdc–F)]3[BF4]6}n. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://mediatum.ub.tum.de/download/1116568/1116568.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |