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Redox‐Neutral Dual Functionalization of Electron‐Deficient Alkenes
| Content Provider | Semantic Scholar |
|---|---|
| Author | Pettersson, Fredrik Bergonzini, Giulia Cassani, Carlo Wallentin, Carl-Johan |
| Copyright Year | 2017 |
| Abstract | Visible-light photoredox catalysis has been utilized in a new multicomponent reaction forming β-functionalized δ-diketones under mild conditions in an operationally convenient manner. Single-electron reduction of in situ generated carboxylic acid derivatives forms acyl radicals that react further via 1,2-acylalkylation of olefins in an intermolecular, three-components cascade reaction, giving valuable synthetic entities from readily available starting materials. A diverse set of substrates has been used, demonstrating robust methodology with broad substrate scope. |
| Starting Page | 7444 |
| Ending Page | 7447 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1002/chem.201701589 |
| PubMed reference number | 28402066 |
| Journal | Medline |
| Volume Number | 23 |
| Alternate Webpage(s) | https://ftp.ncbi.nlm.nih.gov/pub/pmc/oa_pdf/4a/c1/CHEM-23-7444.PMC5574022.pdf |
| Journal | Chemistry |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |