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An unexpected role of a trace amount of water in catalyzing proton transfer in phosphine-catalyzed (3 + 2) cycloaddition of allenoates and alkenes.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Xia, Yuanzhi Liang, Yong Min Chen, Yuanyuan Wang, Ming Jiao, Lei Huang, Feng Liu, Song Li, Yahong Yu, Zhi-Xiang |
| Copyright Year | 2007 |
| Abstract | Through the joint forces of computation and experiment, the detailed mechanism of the Lu phosphine catalyzed (3 + 2) cycloaddition of allenoates and alkenes has been elucidated. The overall potential energy surface of the Lu (3 + 2) reaction has been computed. More importantly, theory and experiment have confirmed that a trace amount of water plays a critical role in assisting the process of [1,2] proton shift in the Lu reaction. |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/ja068215h |
| PubMed reference number | 17319666 |
| Journal | Medline |
| Volume Number | 129 |
| Issue Number | 12 |
| Alternate Webpage(s) | http://www.chem.pku.edu.cn/zxyu/docs/2018-10/20181010154240829668.pdf |
| Alternate Webpage(s) | http://www.chem.pku.edu.cn/zxyu/research.files/parper/An%20Unexpected%20Role%20of%20a%20Trace%20Amount%20of%20Water%20in%20Catalyzing%20Proton.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/ja068215h |
| Journal | Journal of the American Chemical Society |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |