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Dichloridobis(2-methoxydibenzo[c,e][1,2]oxaphosphorine-κP)platinum(II) trichloromethane solvate
| Content Provider | Semantic Scholar |
|---|---|
| Author | Holczbauer, Tamás Keglevich, György Kerényi, Andrea Czugler, Mátyás |
| Copyright Year | 2009 |
| Abstract | The title compound, [PtCl(2)(C(13)H(11)O(2)P)(2)]·CHCl(3), has a rare PtCl(2) bridging of two dibenzooxaphospho-rine ligands through the metal atom. The Pt(II) ion is in a slightly distorted square-planar environment. The trichloro-methane solvent mol-ecule shows rotational disorder (major occupancy is 0.75) and is placed near to the inversion centre at (1/2, 1/2, 0) in channels parallel to the a axis. The solvent mol-ecule is linked to the complex mol-ecule via inter-molecular bifurcated C-H⋯Cl and C-H⋯O hydrogen bonds. The crystal structure is further stabilized by π-π inter-actions involving the benzene rings, with a centroid-centroid distance of 3.658 (8) Å. |
| Starting Page | m347 |
| Ending Page | m348 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| PubMed reference number | 21582112 |
| DOI | 10.1107/S1600536809006643 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Volume Number | 65 |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536809006643 |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Ions Ligands Methane:MCnc:Pt:Bld:Qn Mole, unit of measurement Peripheral T-Cell Lymphoma Ring device naphthalenetetracarboxylic acid anhydride solvate |
| Content Type | Text |
| Resource Type | Article |
